G. Szalóki, K. Miqueu, D. Bourissou, “Silver-mediated intramolecular P–C coupling”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>78

This article is cited in 4 papers

Communications

Silver-mediated intramolecular P–C coupling

G. Szalóki^a, K. Miqueu^b, D. Bourissou^a

^a CNRS/Université Toulouse III - Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée, Toulouse, France
^b CNRS/Université de Pau et des Pays de l’Adour, Institut des Sciences Analytiques et de Physico-Chimie pour l’Environnement et les Matériaux, Pau Cedex, France

Abstract: Silver(I) salts mimic copper(I) but not gold(I) salts in the reaction with peri-iodo naphthyldiisopropylphosphine. The formation of the corresponding peri-cyclic phosphonium derivatives represents the first example of silver-mediated P–C coupling through a two-electron redox sequence.

Keywords: silver, complexes, cross-coupling, oxidative addition, phosphonium salts, DFT, naphthalene, peri substitution.

Language: English

DOI: 10.1016/j.mencom.2022.01.025

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