A. V. Maleeva, I. V. Ershova, O. Yu. Trofimova, K. V. Arsenyeva, I. A. Yakushev, A. V. Piskunov, “Near-IR absorbing donor–acceptor charge-transfer gallium complex, an example from non-transition metal chemistry”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>83

This article is cited in 21 papers

Communications

Near-IR absorbing donor–acceptor charge-transfer gallium complex, an example from non-transition metal chemistry

A. V. Maleeva^a, I. V. Ershova^a, O. Yu. Trofimova^a, K. V. Arsenyeva^a, I. A. Yakushev^b, A. V. Piskunov^a

^a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Gallium(III) catecholates with bipyridine ligand [(3,5-Cat)Ga(bipy)2]I and (3,6-Cat)GaI(bipy) (Cat is di-tert-butylcatecholate) were synthesized and characterized by single-crystal X-ray diffraction. The appearance of near-infrared ligand-to-ligand charge transfer for pentacoordinate complex was observed.

Keywords: gallium, redox-active ligand, catecholate, diimine, X-ray diffraction, electronic spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2022.01.027

	*Supplementary materials:*
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