A. V. Murashkina, D. S. Kuliukhina, A. D. Averin, A. S. Abel, E. N. Savelyev, B. S. Orlinson, I. A. Novakov, C. R. Correia, I. P. Beletskaya, “A comparison of homogeneous and heterogeneous copper catalyzed arylation of amines”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>91

This article is cited in 10 papers

Communications

A comparison of homogeneous and heterogeneous copper catalyzed arylation of amines

A. V. Murashkina^a, D. S. Kuliukhina^a, A. D. Averin^a, A. S. Abel^a, E. N. Savelyev^b, B. S. Orlinson^b, I. A. Novakov^b, C. R. Correia^c, I. P. Beletskaya^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Volgograd State Technical University, Volgograd, Russian Federation
^c Universidade Estadual de Campinas, Campinas, São Paulo, Brazil

Abstract: Comparison of the homogeneous and heterogeneous copper-catalyzed arylation of model primary amines with (hetero)-aryl iodides in DMSO revealed a comparable efficiency of CuI and commercially available unsupported copper nanoparticles (25 nm size) in the presence of 2-isobutyryl-cyclohexanone or L-proline.

Keywords: amination, copper, homogeneous catalysis, heterogeneous catalysis, nanoparticles, iodoarenes.

Language: English

DOI: 10.1016/j.mencom.2022.01.029

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