I. R. Mironova (Knyazeva), V. V. Syakaev, W. D. Habicher, A. R. Burilov, “Novel first-generation dendrimers on calix[4]resorcinol core equipped with multiple triazole units”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>103

This article is cited in 2 papers

Communications

Novel first-generation dendrimers on calix[4]resorcinol core equipped with multiple triazole units

I. R. Mironova (Knyazeva)^a, V. V. Syakaev^a, W. D. Habicher^b, A. R. Burilov^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Institute of Organic Chemistry, Dresden University of Technology, Dresden, Germany

Abstract: Novel first-generation dendrimers on the calix[4]resorcinol core with four branches each containing multiple 1,2,3-triazole units have been synthesized in one-step by acid catalyzed condensation of resorcinols with a new aldehyde dendron, namely, 4-{3,5-bis[(1-benzyl-1H-1,2,3-triazol-4-yl)- methoxy]benzyloxy}benzaldehyde (obtained by alkyne–azide cycloaddition). The reaction proceeds stereoselectively to form rccc-diastereoisomers in high yields.

Keywords: dendrimers, dendrons, calix[4]resorcinols, 1,2,3-triazoles, condensation, click reaction.

Language: English

DOI: 10.1016/j.mencom.2022.01.033

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