P. V. Primakov, G. Denisov, V. V. Novikov, O. L. Lependina, A. A. Korlyukov, Yu. V. Nelyubina, “Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>105

This article is cited in 12 papers

Communications

Calcium-based coordination polymers from a solvothermal synthesis of HKUST-1 in 3D printed autoclaves

P. V. Primakov^ab, G. Denisov^a, V. V. Novikov^a, O. L. Lependina^a, A. A. Korlyukov^a, Yu. V. Nelyubina^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: A mixed-metal 1D coordination polymer [CaCu(HBTC)₂(H2O)₈]_n (where H₃BTC – benzene-1,3,5-tric arboxylic acid) was obtained in a solvothermal synthesis of a well-known copper-containing metal–organic framework [Cu₃(BTC)₂(H₂O)₃]_n (HKUST-1) in autoclaves 3D-printed from commercial polypropylene. This material was a source of calcium ions, apparently, leaking from a colorant (calcium carbonate) promoted by glacial acetic acid as a modulator used to produce large single crystals of HKUST-1. This finding was confirmed by elemental analysis and a model experiment that resulted in a new calcium-based 1D coordination polymer [Ca(H₂BTC)₂(H₂O)₅]_n under the same solvothermal conditions with no copper or calcium salts put into a 3D-printed autoclave.

Keywords: 3D printing, 3D printed reactionware, autoclave, crystal structure, metal–organic coordination polymer, polypropylene, solvothermal synthesis, X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2022.01.034

	*Supplementary materials:*
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