V. V. Sharutin, O. K. Sharutina, A. N. Efremov, S. A. Adonin, “Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine”, Mendeleev Commun., 2022, Volume 32, Issue 1,Pages <nobr>109

This article is cited in 3 papers

Communications

Stoichiometry-dependent oxidation of tris(2-methoxyphenyl)antimony with diiodine

V. V. Sharutin^a, O. K. Sharutina^a, A. N. Efremov^a, S. A. Adonin^ab

^a South Ural State University (National Research University), Chelyabinsk, Russian Federation
^b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The reaction of 2-methoxyphenyllithium with SbCl₃ affords tris(2-methoxyphenyl)antimony. Its treatment with equimolar amount of I₂ results in stiborane (2-MeOC₆H₄)₃SbI₂, while heating with 2 equivalents of I₂ leads to iodotris(2-methoxyphenyl)stibonium triiodide [(2-MeOC₆H₄)₃SbI]⁺ [I₃]^– featuring halogen bonding in solid state.

Keywords: antimony, organometallic compounds, non-covalent interactions, crystal structure, organoantimony compounds, iodine.

Language: English

DOI: 10.1016/j.mencom.2022.01.035

	*Supplementary materials:*
		Supplementary_data_1.pdf	854.6 Kb