K. M. Borisov, A. A. Kalinina, E. S. Bokova, M. N. Ilyina, G. V. Cherkaev, E. A. Tatarinova, S. A. Milenin, A. V. Bystrova, M. Moeller, A. M. Muzafarov, “Synthesis and properties of MQ resins with phenyl groups in monofunctional units”, Mendeleev Commun., 2022, Volume 32, Issue 2,Pages <nobr>164

This article is cited in 4 papers

Communications

Synthesis and properties of MQ resins with phenyl groups in monofunctional units

K. M. Borisov^abc, A. A. Kalinina^ab, E. S. Bokova^c, M. N. Ilyina^b, G. V. Cherkaev^a, E. A. Tatarinova^a, S. A. Milenin^a, A. V. Bystrova^ab, M. Moeller^b, A. M. Muzafarov^ab

^a N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Kosygin Russian State University, Moscow, Russian Federation

Abstract: MQ resins have been prepared in acetic acid as an active medium from dimethylphenyl- or methyldiphenylethoxy-silane as the M-components and tetraethoxysilane as the Q-component. All prepared samples with M/Q ratios of 1:1, 1:1.5, 1:2, 1:3, and 1:4 were well soluble in organic solvents like toluene and THF. Compared to MQ resins with trimethylsilyl group as the M-component, the new MQ resins with phenyl substituents may possess improved compatibility to thermoplastic polymers, rubbers and coating formulations.

Keywords: polycondensation, active media, MQ resins, MQ copolymers, organosiloxanes.

Language: English

DOI: 10.1016/j.mencom.2022.03.003

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