T. A. Shestimerova, M. A. Bykov, A. V. Grigor'eva, Zh. Wei, E. V. Dikarev, A. V. Shevelkov, “Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions”, Mendeleev Commun., 2022, Volume 32, Issue 2,Pages <nobr>194

This article is cited in 3 papers

Communications

Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions

T. A. Shestimerova^a, M. A. Bykov^a, A. V. Grigor'eva^ab, Zh. Wei^c, E. V. Dikarev^c, A. V. Shevelkov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Department of Materials Science, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c Department of Chemistry, University at Albany, Albany, NY, USA

Abstract: The amantadinium iodoacetatobismuthate(III) [C₁₀H₁₅NH₃·(CH₃)₂CO]₂[BiI_3.67(CH₃COO)_1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains [BiI_3.67(CH₃COO)_1.33]^2– and the countercations [C₁₀H₁₅NH₃·(CH₃)₂CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV.

Keywords: Amantadine, Iodide, Bismuth, Acetate, Perovskite photovoltaics.

Language: English

DOI: 10.1016/j.mencom.2022.03.014

	*Supplementary materials:*
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