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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 2, Pages 238–240 (Mi mendc625)

This article is cited in 4 papers

Communications

Controlling monomer sequence distribution in RAFT polymerization of styrene and acrylic acid

R. V. Tomsa, N. I. Prokopova, K. O. Mineevab, A. V. Plutalovab, E. V. Chernikovab

a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Continuous and semicontinuous RAFT copolymerization was first applied to synthesize well-defined copolymers of styrene and acrylic acid. The obtained copolymers have a different monomer sequence distribution due to different ways of adding acrylic acid to the reaction medium.

Keywords: reversible addition–fragmentation chain-transfer (RAFT) polymerization, copolymerization, random copolymers, block copolymers, gradient copolymers.

Language: English

DOI: 10.1016/j.mencom.2022.03.028



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