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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 2, Pages 247–248 (Mi mendc628)

This article is cited in 4 papers

Communications

Synthesis and hydrodynamic properties of star poly(2-alkyl-2-oxazolines) and poly(2-alkyl-2-oxazines) based on sulfochlorinated calix[4]arene initiator

A. N. Blokhin, T. Yu. Kirila, N. D. Kozina, A. B. Razina, A. P. Filippov, A. V. Tenkovtsev

Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russian Federation

Abstract: New four-arm star poly(2-alkyl-2-oxazolines) and poly(2-alkyl-2-oxazines) were synthesized using sulfochlorinated calix[4]arene derivative as a multifunctional initiator. Their characteristics were investigated by gel permeation chromatography, light scattering and viscometry. The polymer stars obtained were shown to have well-defined architecture and high intramolecular density.

Keywords: cationic polymerization, ring-opening polymerization, polyoxazoline, polyoxazine, star polymer, calixarene, sulfonyl chloride.

Language: English

DOI: 10.1016/j.mencom.2022.03.031



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