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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 2, Pages 256–257 (Mi mendc631)

This article is cited in 2 papers

Communications

Rhodium-catalyzed regioselective cross-coupling of styrene oxides with arylboronic acids in aqueous γ-valerolactone

J. Zhang, Yu. Chen, X. Luo, Zh. Wen

College of Pharmaceutics, Jinhua Polytechnic, Jinhua, P.R. China

Abstract: A simple and regioselective cross-coupling of styrene oxides with arylboronic acids in the presence of Rh(PPh3)3Cl in biomass-derived γ-valerolactone has been developed. The reactions proceeded smoothly to give 1,2-diaryl ethanols as the predominant products in moderate to good yields.

Keywords: styrene oxides, arylboronic acids, rhodium catalysis, regioselectivity, γ-valerolactone, green solvent.

Language: English

DOI: 10.1016/j.mencom.2022.03.034



© Steklov Math. Inst. of RAS, 2025