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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 2, Pages 268–270 (Mi mendc636)

This article is cited in 2 papers

Communications

Synthesis and optical properties of new chalcones containing 4-[bis(2-hydroxyethyl)amino]phenyl fragment

A. N. Chukhlantsevaab, M. V. Dmitrievb, O. A. Maiorovaa, E. V. Shklyaevab, G. G. Abashevab

a Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm, Russian Federation
b Perm State National Research University, Perm, Russian Federation

Abstract: New chalcones with 4-[bis(2-hydroxyethyl)amino] phenyl fragment were obtained from 4-[bis(2-acetoxyethyl) amino]- benzaldehyde by the Claisen–Schmidt reaction. From their UV-VIS absorption and emission spectra, optical band gap values were calculated based on the Stokes shifts as well as the molar absorption coefficients and fluorescence quantum yields were estimated. The dependence of the absorption and emission maxima on solvent polarity and pH was evaluated.

Keywords: Chalcones, Chromophore, Solvatochromism, quantum yield, thiophene derivative, carbazole.

Language: English

DOI: 10.1016/j.mencom.2022.03.039



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