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Mendeleev Commun., 2025 Volume 35, Issue 3, Pages 351–352 (Mi mendc6429)

Communications

Transfer hydrodechlorination of chlorobenzene over Ni–Mo sulfide system and effect of HCl neutralizer

A. S. Romanov, N. S. Nesterov, A. A. Salomatina, O. V. Klimov, V. P. Pakharukova, A. A. Philippov, I. V. Kozhevnikov, A. M. Chibiryaev, O. N. Martyanov

G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Abstract: Catalytic transfer hydrodechlorination of chlorobenzene using 2-propanol as the hydrogen donor and a mixed Ni–Mo sulfide phase deposited on alumina as the catalyst is studied at temperatures 250–300 °C. When triethylamine is applied as the HCl neutralizer, benzene is the only product, whereas with inorganic bases (iso)propylbenzenes are also formed.

Keywords: transfer hydrodechlorination, nickel–molybdenum sulfide system, 2-propanol, chlorobenzene, benzene.

Received: 26.09.2024
Accepted: 09.12.2024

Language: English

DOI: 10.71267/mencom.7630



© Steklov Math. Inst. of RAS, 2025