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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 3, Pages 341–343 (Mi mendc657)

This article is cited in 3 papers

Communications

Design of star-shaped azido-containing polymer

A. E. Tarasov, E. O. Perepelitsina, L. B. Romanova, A. V. Darovskikh, V. S. Smirnov, E. R. Badamshina, Yu. M. Mikhailov

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: An efficient synthesis of the new star-shaped polymer with azido-containing oligomer rays is based on construsion of these rays on the β-cyclodextrin nitrate core employing 3,3-bis(azidomethyl)oxetane as the key reactant. The formation of star-shaped structure was proved. Thermal and optical properties of the synthesized polymers were assessed.

Keywords: β-cyclodextrin partial nitrate, 3,3-bis(azidomethyl)oxetane, star-shaped polymers, cationic ring-opening polymerization, energetic materials.

Language: English

DOI: 10.1016/j.mencom.2022.05.016



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