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Mendeleev Commun., 2022 Volume 32, Issue 3, Pages 349–350 (Mi mendc660)
Communications

Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane

D. A. Kulagina, A. S. Goryaev, I. N. Chernyshov, S. V. Sysolyatin

Institute for Problems of Chemical & Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, Russian Federation

Abstract: Nitration of N-benzylated 2,4,6,8,10,12-hexaazaisowurtzitane derivatives occurs selectively at para-positions of the benzyl groups. The best reagent for this reaction is ammonium nitrate in sulfuric acid.

Keywords: hexaazaisowurtzitanes, cage compounds, nitration, nitrating mixtures, benzyl groups, selective reaction.

Language: English

DOI: 10.1016/j.mencom.2022.05.019


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