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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 3, Pages 377–378 (Mi mendc669)

This article is cited in 1 paper

Communications

Molecular structure and photocatalytic properties of the pentaphenylantimony–3,5-dinitrosalicylic acid reaction product

Yu. O. Pupkova(Gubanova)a, V. V. Sharutina, O. K. Sharutinaa, A. S. Fominykhb, O. S. Eltsovc

a Institute of Natural Sciences and Mathematics, South Ural State University, Chelyabinsk, Russian Federation
b Research School of Chemistry and Applied Biomedical Sciences, Tomsk, Russian Federation
c Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation

Abstract: Reaction between pentaphenylantimony and 3,5-dinitro-salicylic acid involves both hydroxy and carboxy groups to form the complex containing an anion with the six-membered metallocycle and Ph4Sb+ counter-cation. The molecular structure of the reaction product has been established by X-ray analysis. The photocatalytic properties have been studied by the methylene blue photodegradation

Keywords: pentaphenylantimony, 3,5-dinitrosalicylic acid, organoantimony compounds, X-ray analysis, molecular structure, photocatalytic properties.

Language: English

DOI: 10.1016/j.mencom.2022.05.028



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