M.-x. Xu, K.-M. Zhang, “Rongalite-promoted transition metal-free synthesis of <i>S</i>-aryl phosphorothioates”, Mendeleev Commun., 2022, Volume 32, Issue 3,Pages <nobr>390

This article is cited in 4 papers

Communications

Rongalite-promoted transition metal-free synthesis of S-aryl phosphorothioates

M.-x. Xu^a, K.-M. Zhang^ab

^a Jiangsu Police Institute, Nanjing, P.R. China
^b Nanjing Institute of Technology, Nanjing, P.R. China

Abstract: The improved procedure for the synthesis of S-aryl phosphorothioates from dialkyl phosphites (H-phosphonates), aryl iodides and elemental sulfur deals with the application of rongalite (sodium hydroxy-methanesulfinate) as the radical promoter. The reactions proceeded smoothly to give S-aryl phosphorothioates in good yields.

Keywords: rongalite, phosphorothioates, arylation, radical process, aryl halides, sulfur.

Language: English

DOI: 10.1016/j.mencom.2022.05.033

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