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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 4, Pages 482–484 (Mi mendc701)

Communications

Cyclopentadienyl rhodium(III) complexes as catalysts for the insertion of phenyldiazoacetate into E−H bonds

A. A. Komarovaa, D. V. Muratova, D. S. Perekalinab

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Abstract: Rhodium(III) complexes catalyze the insertion of carbenoids generated from diazo compounds into E−H bonds (E = B, Si, N, but not C), although less efficiently than classical rhodium(II) carboxylates, despite formally higher oxidation state of the metal.

Keywords: rhodium complexes, diazo compounds, insertion, catalysis, cyclopentadienyl ligands.

Language: English

DOI: 10.1016/j.mencom.2022.07.017



© Steklov Math. Inst. of RAS, 2025