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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2022 Volume 32, Issue 4, Pages 551–553 (Mi mendc723)

This article is cited in 3 papers

Communications

Synthesis and properties of dicationic ionic liquids with pentasiloxane linker

V. G. Krasovskiya, O. B. Gorbatsevichb, E. V. Talalaevab, L. M. Glukhova, E. A. Chernikovaa, L. M. Kustovac

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: New dicationic ionic liquids with pentasiloxane linker between two imidazolium moieties and bis(trifluoromethyl-sulfonyl)imide anions were synthesized; their melting points, glass transition temperatures and viscosities were measured, and thermal and hydrolytic stabilities were investigated. The dependence of the properties of these ionic liquids on the length of the siloxane linker in the cation part is revealed.

Keywords: dicationic ionic liquids, imidazolium compounds, pentasiloxane linker, thermal stability, viscosity, hydrolytic stability.

Language: English

DOI: 10.1016/j.mencom.2022.07.039



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