D. A. Gulyaev, N. V. Gadimov, N. P. Gritsan, E. M. Kadilenko, P. G. Shangin, M. A. Syroeshkin, E. A. Sosunov, E. V. Tretyakov, “Polyfluorinated Blatter radicals”, Mendeleev Commun., 2025, Volume 35, Issue 2,Pages <nobr>169–171</nobr>

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Mendeleev Commun., 2025 Volume 35, Issue 2, Pages 169–171 (Mi mendc7255)

Communications

Polyfluorinated Blatter radicals

D. A. Gulyaev^a, N. V. Gadimov^ab, N. P. Gritsan^c, E. M. Kadilenko^c, P. G. Shangin^a, M. A. Syroeshkin^a, E. A. Sosunov^bd, E. V. Tretyakov^a

^a N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
^b D. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
^c V. V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
^d N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Abstract: The first benzotriazinyl radicals containing fluorine atoms in both aryl substituents were synthesized from polyfluorophenylhydrazines and 4-fluoro-N-phenylbenzimidoyl chloride. Their crystal structure and magnetic properties were studied thus revealing strong antiferromagnetic interactions (J/kB from –160 to –185 K).

Keywords: organofluorine compounds, heterocycles, organic radicals, 1,2,4-benzotriazin-4-yls, magnetostructural correlations.

Received: 14.01.2025
Accepted: 21.01.2025

Language: English

DOI: 10.71267/mencom.7724

	*Supplementary materials:*
		Supplementary_data_1.pdf	4.4 Mb

© Steklov Math. Inst. of RAS, 2025