E. A. Kravchenko, A. A. Gippius, A. V. Tkachev, M. V. Mastryukov, M. N. Brekhovskikh, “The purity of SnCl4 as monitored by 35Cl nuclear quadrupole resonance”, Mendeleev Commun., 2022, Volume 32, Issue 4,Pages 567

This article is cited in 1 paper

Communications

The purity of SnCl₄ as monitored by ³⁵Cl nuclear quadrupole resonance

E. A. Kravchenko^a, A. A. Gippius^bc, A. V. Tkachev^b, M. V. Mastryukov^a, M. N. Brekhovskikh^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b P.N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The nuclear quadrupole resonance (NQR) spectroscopy was used to control the comparative purity of three SnCl₄ samples subjected to successive stages of deep purification. The results showed that at 77 K the samples were identical in purity degree due to the ‘freezing’ of impurities into a separate fraction not affecting the perfection of the SnCl₄ crystal lattice. The results of relaxation measurements suggest that paramagnetic impurity atoms (Fe and Cr) contained in the samples in small amounts might be embedded into the crystal lattice causing extremely long spin–spin relaxation time.

Keywords: nuclear quadrupole resonance, impurities, tin chloride, purification, mass spectrometry.

Language: English

DOI: 10.1016/j.mencom.2022.07.044