A. S. Popova, N. K. Ogarkova, S. S. Shapovalov, I. V. Skabitsky, E. K. Kultyshkina, I. A. Yakushev, M. N. Vargaftik, “Synthesis, structure and catalytic properties of Pd<sup>ii</sup>-based bimetallic complexes with ferrocenecarboxylic acid”, Mendeleev Commun., 2022, Volume 32, Issue 5,Pages <nobr>576

This article is cited in 5 papers

Communications

Synthesis, structure and catalytic properties of Pdⁱⁱ-based bimetallic complexes with ferrocenecarboxylic acid

A. S. Popova^ab, N. K. Ogarkova^b, S. S. Shapovalov^a, I. V. Skabitsky^a, E. K. Kultyshkina^b, I. A. Yakushev^a, M. N. Vargaftik^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Abstract: Novel highly soluble palladium-based complexes with ferrocenecarboxylic acid of general formula [Pd(lut)₂(FcCOO)₂] (lut is 2,6-or 3,4-lutidines) were synthesized and structurally characterized by single-crystal X-ray diffraction. The catalytic oxidation of 1,2-diphenyl-acetylene with these complexes gave dibenzo[a,e]pentalene derivative along with other products.

Keywords: palladium complexes, ferrocenecarboxylic acid, ligand exchange, XRD analysis, homogeneous catalysis, diphenylacetylene, dibenzo[a, e]pentalene.

Language: English

DOI: 10.1016/j.mencom.2022.09.002

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