V. A. Dodonov, A. A. Skatova, I. L. Fedushkin, “Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene”, Mendeleev Commun., 2022, Volume 32, Issue 5,Pages <nobr>582

This article is cited in 5 papers

Communications

Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene

V. A. Dodonov, A. A. Skatova, I. L. Fedushkin

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Abstract: Reactivity of ytterbium and magnesium complexes of gallylenes against carbon dioxide and diphenylketene has been assessed. Ytterbium complex of redox-active gallylene [{(dpp-bian)Ga}₂Yb(DME)₂] (dpp-bian = 1,2-bis[(2,6-diiso-propylphenyl)imino]acenaphthene) on treatment with CO₂ gives complex [(dpp-bian)Ga(DME)Me], while the treatment of magnesium-stabilized gallylene[{(dpp-bian)Ga}₂Mg(DME)₂] with Ph₂CCO affords cycloadduct [(dpp-bian)(Ph₂CCO)GaMe].

Keywords: gallylenes, carbon dioxide, ketenes, non-innocent α-diimine ligands, cycloaddition, magnesium, ytterbium, X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2022.09.004

	*Supplementary materials:*
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