M. A. Bondarenko, M. I. Rakhmanova, A. S. Novikov, M. N. Sokolov, S. A. Adonin, “Bi- or trinuclear 2-iodobenzoate complexes of Zn<sup>ii</sup>: crystal structures and luminescence”, Mendeleev Commun., 2022, Volume 32, Issue 5,Pages <nobr>585

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Communications

Bi- or trinuclear 2-iodobenzoate complexes of Znⁱⁱ: crystal structures and luminescence

M. A. Bondarenko^a, M. I. Rakhmanova^a, A. S. Novikov^b, M. N. Sokolov^a, S. A. Adonin^a

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation

Abstract: Reactions of zinc nitrate with 2-iodobenzoic acid (2-IBA) and different pyridines result in binuclear Znⁱⁱ carboxylate complexes [Zn₂(2-IBA)₄L₂], where L = Py, 3-MePy and 3,5-Me₂Py, while in the case of 2,4,6-Me₃Py, trinuclear (2,4,6-Me₃PyH)₂[Zn₃(2-IBA)₆(OH)₂] is formed.

Keywords: zinc, carboxylates, non-covalent interactions, crystal structure, luminescence.

Language: English

DOI: 10.1016/j.mencom.2022.09.005

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