M.-x. Xu, K.-M. Zhang, “Rongalite-promoted synthesis of β-keto sulfones <i>via</i> radical cascade reaction”, Mendeleev Commun., 2022, Volume 32, Issue 5,Pages <nobr>627

This article is cited in 1 paper

Communications

Rongalite-promoted synthesis of β-keto sulfones via radical cascade reaction

M.-x. Xu^a, K.-M. Zhang^ab

^a Jiangsu Police Institute, Nanjing, P.R. China
^b Nanjing Institute of Technology, Nanjing, P.R. China

Abstract: Direct arylsulfonylation of arylethenes with aryl iodides and sodium metabisulfite to access β-keto sulfones is described. In this reaction, rongalite (sodium hydroxymethanesulfinate) and sodium metabisulfite serve as the radical promoter and the sulfur dioxide surrogate, respectively.

Keywords: rongalite, sodium metabisulfite, aryl halides, alkenes, radical cascade, β-keto sulfones.

Language: English

DOI: 10.1016/j.mencom.2022.09.019

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