I. Yu. Skvortsov, L. A. Varfolomeeva, M. S. Kuzin, A. F. Vashchenko, E. V. Chernikova, R. V. Toms, V. G. Kulichikhin, “Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties”, Mendeleev Commun., 2022, Volume 32, Issue 5,Pages <nobr>652

This article is cited in 9 papers

Communications

Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties

I. Yu. Skvortsov^a, L. A. Varfolomeeva^a, M. S. Kuzin^a, A. F. Vashchenko^a, E. V. Chernikova^ab, R. V. Toms^ac, V. G. Kulichikhin^a

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Abstract: Polyacrylonitrile terpolymers based on acrylonitrile, acrylic acid, and methyl acrylate were synthesized by reversible addition–fragmentation chain-transfer polymerization with varying the monomer addition sequence during the synthesis. The monomer introduction sequence in the synthesis of a ternary copolymer significantly affects both the rheological properties of solutions and the strength of obtained fibers.

Keywords: polyacrylonitrile, reversible addition–fragmentation chain-transfer polymerization, comonomer sequence, rheology, fiber spinning.

Language: English

DOI: 10.1016/j.mencom.2022.09.028