F. Yu. Vyalba, A. V. Ivantsova, K. A. Zhdanova, M. N. Usachev, M. A. Gradova, N. A. Bragina, “Synthesis of conjugates of 5,15-disubstituted aminoporphyrins and terpyridine derivatives with potential chelating properties”, Mendeleev Commun., 2022, Volume 32, Issue 5,Pages <nobr>675

This article is cited in 5 papers

Communications

Synthesis of conjugates of 5,15-disubstituted aminoporphyrins and terpyridine derivatives with potential chelating properties

F. Yu. Vyalba^a, A. V. Ivantsova^a, K. A. Zhdanova^a, M. N. Usachev^a, M. A. Gradova^b, N. A. Bragina^a

^a M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
^b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: meso-Arylporphyrin containing two external chelating 2,2':6',2'-terpyridine fragments and its zinc complex were synthesized. The key step comprised the amide bond formation between the porphyrin diamine derivative and 4'-(4-carboxyphenyl)-2,2':6',2'-terpyridine. The compounds obtained seem to be potent for photodynamic therapy and diagnosis.

Keywords: porphyrins, terpyridine, Zn complexes of porphyrins, photodiagnostics, photodynamic therapy, chelating groups.

Language: English

DOI: 10.1016/j.mencom.2022.09.036

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