D. V. Sedlova, E. S. Osipova, E. I. Gutsul, I. A. Godovikov, O. A. Filippov, E. S. Shubina, N. V. Belkova, “Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)]”, Mendeleev Commun., 2024, Volume 34, Issue 2,Pages 192

Communications

Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)₂(μ-CO)···Pd(^t-BuPCP)]

D. V. Sedlova^ab, E. S. Osipova^a, E. I. Gutsul^a, I. A. Godovikov^a, O. A. Filippov^a, E. S. Shubina^a, N. V. Belkova^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region, Russian Federation

Abstract: The interaction of bimetallic (^t-BuPCP)Pd···(OC)M(CO)₂ Cp (M = Mo, W) complexes with PhSiH₃ leads to an efficient heterolytic splitting of Si–H bond that is a primary step in catalytic hydrosilylation of CO₂. The reaction can be stopped at the formate level in the presence of the above complexes while proceeds further when catalyzed by (^t-BuPCP)PdH.

Keywords: bimetallic catalysis, pincer complexes, carbon dioxide, hydrosilylation, reaction mechanism, IR spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2024.02.010

	*Supplementary materials:*
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