N. A. Korobeynikov, A. N. Usoltsev, M. N. Sokolov, S. A. Adonin, “Iodobismuthate(iii) complex with coordinated triiodide ligand and 3D supramolecular structure”, Mendeleev Commun., 2022, Volume 32, Issue 6,Pages <nobr>786

Communications

Iodobismuthate(iii) complex with coordinated triiodide ligand and 3D supramolecular structure

N. A. Korobeynikov, A. N. Usoltsev, M. N. Sokolov, S. A. Adonin

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Iodobismuthate complex (1-Me-3-ClPy)₃[Bi₂I₈(I₃)] features the presence of coordinated triiodide ligand. The system of I∙∙∙I non-covalent interactions yields in 3D supramolecular structure. This complex reveals high thermal stability (>100 °C) and relatively narrow optical band gap (1.55 eV), and it can be considered as promising candidate for testing as light absorber in photovoltaic devices.

Keywords: bismuth, halide complexes, semiconductors, non-covalent interactions.

Language: English

DOI: 10.1016/j.mencom.2022.11.026

	*Supplementary materials:*
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