V. S. Zimarev, I. V. Chuchelkin, K. N. Gavrilov, I. A. Zamilatskov, V. A. Tafeenko, B. V. Lokshin, N. S. Goulioukina, “Neutral dinuclear palladium(II) complex containing chiral P,S-bridging diamidophosphite-thioether ligands”, Mendeleev Commun., 2024, Volume 34, Issue 2,Pages 195

Communications

Neutral dinuclear palladium(II) complex containing chiral P,S-bridging diamidophosphite-thioether ligands

V. S. Zimarev^ab, I. V. Chuchelkin^b, K. N. Gavrilov^b, I. A. Zamilatskov^c, V. A. Tafeenko^a, B. V. Lokshin^d, N. S. Goulioukina^abc

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Department of Chemistry, S.A. Esenin Ryazan State University, Ryazan, Russian Federation
^c A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^d A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: An unusual neutral dinuclear palladium(II) complex with two head-to-head orientated μ-P,S-bridging ligands was obtained by the reaction of Pd(MeCN)₂ Cl₂ with (1R,5R)-3-(4-phenylthiobutoxy)-2,4-diphenyl-2,4-diaza-3-phospha-bicyclo[3.4.0]nonane. The dimeric structure of the complex in the solid state and in solution was thoroughly confirmed using appropriate analytical techniques: single crystal X-ray diffraction analysis, HRMS, FTIR and NMR spectroscopy.

Keywords: dinuclear complexes, palladium(II) complexes, P,S-bidentate ligands, 1,3,2-diazaphospholidines, X-ray crystal structures.

Language: English

DOI: 10.1016/j.mencom.2024.02.011

	*Supplementary materials:*
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