A. S. Soldatenko, I. V. Sterkhova, N. F. Lazareva, “<i>N-</i>(Chlorodimethylsilyl)methyl anilides: synthesis and structure”, Mendeleev Commun., 2022, Volume 32, Issue 6,Pages <nobr>798

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Communications

N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure

A. S. Soldatenko, I. V. Sterkhova, N. F. Lazareva

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: N-(Chlorodimethylsilyl)methyl anilides of formula RC(O)N(C₆H₄X)CH₂SiMe₂Cl (R = Me, Ph; X = H, Me, Cl) were obtained by the reaction of N-TMS-containing anilides with ClCH₂Si(Hal)Me₂ (Hal = F, Cl). The silicon atom in these compounds is pentacoordinate according to the results of NMR and X-ray diffraction analysis.

Keywords: N-(chlorodimethylsilyl)methyl anilides, N-TMS anilides, chloromethyl(dimethyl)halogenosilanes, silicon pentacoordinate, NMR, X-ray diffraction analysis, organosilicon compounds.

Language: English

DOI: 10.1016/j.mencom.2022.11.030

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