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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2021 Volume 31, Issue 1, Pages 27–29 (Mi mendc823)

This article is cited in 4 papers

Communications

Mixed star-shaped POSS-based molecule with hydroxy group-containing units and azobenzene fragments as two types of arms

I. M. Tkachenkoa, P. A. Ledinb, V. V. Shevchenkoa, V. V. Tsukrukb

a Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
b School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA

Abstract: Novel branched organic–inorganic nanoparticles with cubic octahedral silsesquioxane core containing the statistically grafted photoactive azobenzene fragments and 2-hydroxyethyl groups were synthesized via hydrosilylation coupling. Preservation of the photochromic properties of the reactants in the final product was revealed.

Keywords: azo dyes, silsesquioxanes, bifunctional POSS, star molecules, nanoparticle, hydrosilylation, photoisomerization.

Language: English

DOI: 10.1016/j.mencom.2021.01.007



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