S. A. Kuznetsova, S. M. Yunusov, E. A. Khakina, A. V. Naumkin, D. A. Chusov, E. S. Kalyuzhnaya, M. M. Ilyin, V. V. Morozov, A. S. Kashin, Yu. N. Belokon, “Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes”, Mendeleev Commun., 2024, Volume 34, Issue 2,Pages <nobr>204

Communications

Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes

S. A. Kuznetsova^a, S. M. Yunusov^a, E. A. Khakina^a, A. V. Naumkin^a, D. A. Chusov^a, E. S. Kalyuzhnaya^a, M. M. Ilyin^a, V. V. Morozov^ab, A. S. Kashin^c, Yu. N. Belokon^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A novel catalyst based on Pd nanoparticles encapsulated in a chiral crystalline organic salt matrix is prepared from tetrasodium tetrakis(4-sulfonatophenyl)methane and tetrakis[4-(S)-prolinamidophenyl]methane in water at room temperature under hydrogen atmosphere. The hydrogenation of p-nitrobenzaldehyde over this catalyst stalls at the stage of p-aminobenzyl alcohol, whereas Pd/C brings the reduction further to p-toluidine.

Keywords: palladium nanoparticles, heterogeneous hydrogenation, nitroarenes, selective reduction, crystal organic salts, stabilization of nanoparticles, ionic frameworks.

Language: English

DOI: 10.1016/j.mencom.2024.02.014

	*Supplementary materials:*
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