M. Chen, L.-Sh. Duan, Yu.-Zh. Liu, “Effect of the structural disorder of T-shaped triazolyl-based coordination network compounds on the pore size and stability”, Mendeleev Commun., 2021, Volume 31, Issue 1,Pages <nobr>62

This article is cited in 1 paper

Communications

Effect of the structural disorder of T-shaped triazolyl-based coordination network compounds on the pore size and stability

M. Chen^abc, L.-Sh. Duan^abc, Yu.-Zh. Liu^a

^a Hubei Key Laboratory of Purification and Application of Plant Anti-Cancer Active Ingredients, Hubei University of Education, Wuhan, Hubei, China
^b Hubei Engineering Technology Center of Environmental Purification Materials, University of Education, Wuhan, Hubei, China
^c Research Center for Environmental Functional Materials and Pollution Control Technology, Hubei University of Education, Wuhan, Hubei, China

Abstract: The coordination network compounds (CNCs) {[M(L_triaz)](DMF)}_n (M is Zn or Co, H₂L_triaz is 5-(4H-1,2,4- triazol-4-yl)benzene-1,3-dicarboxylic acid, and DMF is N,N-dimethylformamide) with crystallographically identifiable disorder were solvothermally synthesized. The effects of structural disorder on the pore size and stability of T-shaped triazolyl-based CNCs were determined for the first time. In contrast to isostructurally ordered ones, the pore sizes of Zn-CNC and Co-CNC changed, and the stability of Zn-CNC was improved.

Keywords: coordination network compounds, structural disorder, pore size, stability, N₂ sorption.

Language: English

DOI: 10.1016/j.mencom.2021.01.018

	*Supplementary materials:*
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