D. V. Pasyukov, A. Yu. Chernenko, K. E. Shepelenko, V. V. Kutyrev, V. N. Khrustalev, V. M. Chernyshev, “3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes”, Mendeleev Commun., 2021, Volume 31, Issue 2,Pages <nobr>176

This article is cited in 10 papers

Communications

3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes

D. V. Pasyukov^a, A. Yu. Chernenko^a, K. E. Shepelenko^a, V. V. Kutyrev^a, V. N. Khrustalev^bc, V. M. Chernyshev^a

^a Platov South-Russian State Polytechnic University, Novocherkassk, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Abstract: Palladium complexes with N-heterocyclic carbene ligands of a new type containing free NH₂ group were obtained by direct palladation of 3-amino-1,4-dialkyl-1,2,4-triazolium salts. These amino-functionalized complexes were found to be a versatile platform for postmodification via reactions of the NH₂ group with acyl and sulfonyl chlorides.

Keywords: 3-amino-1,2,4-triazole, N-heterocyclic carbenes, palladium complexes, postmodification, catalysis.

Language: English

DOI: 10.1016/j.mencom.2021.03.010

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