RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2021 Volume 31, Issue 2, Pages 194–196 (Mi mendc876)

This article is cited in 3 papers

Communications

Synthesis of benzoaza-15(18)-crown-5(6) ethers and study of their complexes with lead(II)

A. D. Zubenkoa, B. V. Egorovab, L. S. Zamuruevab, S. N. Kalmykovb, O. A. Fedorovaa

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Two methods for obtaining of benzoaza-15(18)-crown-5(6) ethers from 1,2-bis(2-iodoethoxy)benzene or diethyl 1,2-phenylenebis(oxy)diacetate have been reported. The ability of the crown ethers to coordinate lead(II) ions has been estimated by potentiometric and NMR methods.

Keywords: benzoaza-15(18)-crown-5(6) ether, macrocyclization, lead(II) ion, complex formation, potentiometric method, NMR spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2021.03.016



© Steklov Math. Inst. of RAS, 2025