T. V. Bogdan, A. E. Koklin, N. V. Mashchenko, V. I. Bogdan, “Conversion of ethanol over calcium stannate catalyst under supercritical conditions”, Mendeleev Commun., 2024, Volume 34, Issue 2,Pages <nobr>218

This article is cited in 4 papers

Communications

Conversion of ethanol over calcium stannate catalyst under supercritical conditions

T. V. Bogdan^ab, A. E. Koklin^a, N. V. Mashchenko^a, V. I. Bogdan^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Ethanol over calcium stannate (CaSnO₃) catalyst under supercritical conditions (400 °C, 120 atm) is transformed mainly into ethanal, ethyl acetate and 2-buten-1-ol. The process is accompanied by crystallization of the amorphous catalyst.

Keywords: ethanol conversion, supercritical conditions, dehydrogenation, aldol condensation, Tishchenko reaction, borrowing hydrogen, calcium stannate, catalyst crystallization.

Language: English

DOI: 10.1016/j.mencom.2024.02.019

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