V. I. Bogdan, A. E. Koklin, I. I. Mishanin, T. V. Bogdan, N. V. Mashchenko, L. M. Kustov, “Increasing the yield of aromatic hydrocarbons in aromatization of <i>n</i>-butane over Ga/H-ZSM-5 zeolite using a palladium membrane”, Mendeleev Commun., 2021, Volume 31, Issue 2,Pages <nobr>230

This article is cited in 4 papers

Communications

Increasing the yield of aromatic hydrocarbons in aromatization of n-butane over Ga/H-ZSM-5 zeolite using a palladium membrane

V. I. Bogdan^ab, A. E. Koklin^a, I. I. Mishanin^a, T. V. Bogdan^ab, N. V. Mashchenko^a, L. M. Kustov^ab

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The successful use of a palladium membrane to enhance the yield of benzene–toluene–xylene (BTX) fraction in n-butane aromatization at 530°C and 95atm on a Ga/H-ZSM-5 catalyst has been shown. Removal of hydrogen from the reaction zone through the palladium membrane led to an increase in both the n-butane conversion and the selectivity of the BTX fraction formation.

Keywords: aromatization, n-butane, palladium membrane, ZSM-5, Ga/H-ZSM-5, zeolite, BTX fraction, supercritical conditions.

Language: English

DOI: 10.1016/j.mencom.2021.03.028