Mendeleev Commun., 2021 Volume 31, Issue 2, Pages 236–238
(Mi mendc890)
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Communications Unusual stereoselectivity of methionine-γ-lyase from Citrobacterfreundii toward diastereomeric (S )-methionine S -oxide N. G. Faleev a ,
M. A. Tsvetikova a ,
M. M. Ilyin a ,
V. S. Yufryakov a ,
N. G. Kolotyrkina b ,
V. V. Kulikova c ,
T. V. Demidkina c ,
K. A. Kochetkov ad a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation c V.A. Engelhardt Institute of Molecular Biology, Russian Academy of Sciences, Moscow, Russian Federation d D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation Abstract:
Using a diastereomeric mixture of (
S )-methionine
S -oxide as an example, kinetic preference of methionine-γ-lyase toward a stereogenic center at the γ-sulfur atom of the (2
S , R
S ) diastereomer was discovered for the first time.
Keywords:
methionine-γ-lyase, stereoselectivity, kinetic resolution, diastereomers, (S )-methionine S -oxide.
Language: English
DOI:
10.1016/j.mencom.2021.03.030
© , 2025
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