A. M. Semenova, M. A. Ezhikova, M. I. Kodess, A. Ya. Zapevalov, A. V. Pestov, “Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates”, Mendeleev Commun., 2021, Volume 31, Issue 2,Pages <nobr>257

This article is cited in 1 paper

Communications

Phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates

A. M. Semenova^a, M. A. Ezhikova^a, M. I. Kodess^ab, A. Ya. Zapevalov^a, A. V. Pestov^ab

^a I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^b Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation

Abstract: A phosgene-free synthesis of symmetric bis(polyfluoroalkyl) carbonates involves the transesterification of diphenyl carbonate with polyfluoroalkanols promoted by stoichiometric amounts of titanium(iv) alkoxides.

Keywords: transesterification, titanium alkoxides, polyfluoalkanols, dialkyl carbonates, organofluorine compounds.

Language: English

DOI: 10.1016/j.mencom.2021.03.038

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