A. B. Mirgorodskaya, R. A. Kushnazarova, F. G. Valeeva, S. S. Lukashenko, A. A. Tyryshkina, L. Ya. Zakharova, O. G. Sinyashin, “Soft nanosystems based on hydroxypiperidinium surfactants as adjuvants and micellar catalysts”, Mendeleev Commun., 2021, Volume 31, Issue 3,Pages <nobr>323

This article is cited in 11 papers

Communications

Soft nanosystems based on hydroxypiperidinium surfactants as adjuvants and micellar catalysts

A. B. Mirgorodskaya, R. A. Kushnazarova, F. G. Valeeva, S. S. Lukashenko, A. A. Tyryshkina, L. Ya. Zakharova, O. G. Sinyashin

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Quantitative parameters characterizing aggregation behaviour and wetting effect of 1-(2-hydroxyethyl)-piperidinium surfactants have been obtained. Their ability to act as adjuvants in herbicidal compositions based on clopyralid has been revealed. The kinetics of alkaline hydrolysis of paraoxon and armine, organophosphorus ecotoxicants, in the surfactant solutions has been explored and it has demonstrated more than 100-fold micellar rate enhancement.

Keywords: hydroxypiperidinium salts, piperidinium salts, surfactants, aggregation, wetting, micellar catalysis, alkaline hydrolysis.

Language: English

DOI: 10.1016/j.mencom.2021.04.014

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