K. V. Arsenyeva, M. G. Chegerev, A. V. Cherkasov, K. I. Pashanova, I. V. Ershova, O. Yu. Trofimova, A. V. Piskunov, “Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp<sub>2</sub>V–germylene coordination”, Mendeleev Commun., 2021, Volume 31, Issue 3,Pages <nobr>330

This article is cited in 6 papers

Communications

Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp₂V–germylene coordination

K. V. Arsenyeva^a, M. G. Chegerev^b, A. V. Cherkasov^a, K. I. Pashanova^a, I. V. Ershova^a, O. Yu. Trofimova^a, A. V. Piskunov^a

^a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Abstract: Digermylene oxide was prepared by hydrolysis of O,N-heterocyclic germylene, and its reactivity was examined in situ. Its treatment with N-heterocyclic carbene produces dianionic digermylene oxide while its reaction with vanadocene gives the dinuclear derivative, a rare example of a compound containing the vanadium–germylene coordination bond. The product structures were confirmed by X-ray diffraction analysis.

Keywords: N-heterocyclic carbene, germylene, vanadocene, o-amidophenolate, X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2021.04.016