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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2021 Volume 31, Issue 3, Pages 330–333 (Mi mendc920)

This article is cited in 6 papers

Communications

Facile synthesis of digermylene oxide and its reactivity towards vanadocene: the first example of Cp2V–germylene coordination

K. V. Arsenyevaa, M. G. Chegerevb, A. V. Cherkasova, K. I. Pashanovaa, I. V. Ershovaa, O. Yu. Trofimovaa, A. V. Piskunova

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Abstract: Digermylene oxide was prepared by hydrolysis of O,N-heterocyclic germylene, and its reactivity was examined in situ. Its treatment with N-heterocyclic carbene produces dianionic digermylene oxide while its reaction with vanadocene gives the dinuclear derivative, a rare example of a compound containing the vanadium–germylene coordination bond. The product structures were confirmed by X-ray diffraction analysis.

Keywords: N-heterocyclic carbene, germylene, vanadocene, o-amidophenolate, X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2021.04.016



© Steklov Math. Inst. of RAS, 2025