N. V. Shvydkiy, D. S. Perekalin, “Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds”, Mendeleev Commun., 2021, Volume 31, Issue 3,Pages <nobr>350

This article is cited in 4 papers

Communications

Cyclobutadiene cobalt complexes as catalysts for insertion of diazo compounds into X–H bonds

N. V. Shvydkiy^a, D. S. Perekalin^ab

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Abstract: Novel cyclobutadiene cobalt complex with labile naphthalene ligand [(C₄Et₄)Co(C₁₀H₈)]PF₆ catalyzes the insertion of ethyl diazoacetate into X–H bonds giving the corresponding products in 15–75% yields. The reaction proceeds with primary and secondary aliphatic amines, hydrosilanes and triethylamine borane but not with anilines and alcohols.

Keywords: cyclobutadiene, cobalt complexes, catalysis, diazo compounds, insertion, organosilicon compounds.

Language: English

DOI: 10.1016/j.mencom.2021.04.022

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