RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2021 Volume 31, Issue 3, Pages 397–399 (Mi mendc942)

This article is cited in 3 papers

Communications

Second generation phenylene dendrimer, 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, as a precursor of a new carbon material

I. A. Khotina, N. S. Kushakova, V. G. Kharitonova, D. V. Kupriyanova, S. A. Babich, A. I. Kovalev

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A second generation phenylene dendrimer, viz. 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, was synthesized by cyclocondensation of 4-acetyl-3′,5′-diphenyl(biphenyl). This compound on heating to 600°C is transformed into substance possessing extremely heat-stable secondary structure. It retains the aromatic structure at this temperature and when heated to 1000°C is converted into material with graphite-like structure.

Keywords: 4-acetyl-3′,5′-diphenyl(biphenyl), phenylene dendrimers, 1,3,5-tris[4-(3,5-diphenylphenyl)phenyl]benzene, thermal stability.

Language: English

DOI: 10.1016/j.mencom.2021.04.038



© Steklov Math. Inst. of RAS, 2025