Abstract:
The mathematical model of electricity and mass transfer processes is based on the governing equations for the concentration of charged particles (ions and cations) in an electrolyte — the Nernst–Planck equations. These equations are supplemented with the equation for the electric field and the equations for a motion of electrolyte as a continuum medium. In this work we have focused on constructing approximations in time for approximate solving unsteady problems. The system of the Nernst-Planck equations is characterized by a quadratic non-linearity. To take info accont this nonlinearity, we propose special schemes of linearization. Computational algorithms are studied using a model problem for a binary electrolyte (two types of charged particles).
Keywords:electricity and mass transfer, the Nernst–Planck equations, difference scheme, quadratic non-inearity.