Abstract:
Isotherms obtained on the basis of a new distribution are compared with isotherms of the famous van der Waals model, using a language easily understood by engineers and undergraduates (without proofs or theorems, which can be found in the given references, but with elementary examples and simple associations). We propose a new interpretation of the van der Waals model. On the Hougen–Watson diagram, the domain where the mixing of gases occurs with maximum rate is indicated. A new distribution is presented, the notion of new ideal gas is introduced, and the invariants of the isotherms introduced by the author are explained.
Keywords:isotherm, isochore, number of collective degrees of freedom,
admissible cluster size, Boltzmann–Maxwell ideal gas, Lagrangian manifold,
tunnel classical operator, focal point, jamming effect, critical point, opalescence.