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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2022 Volume 13, Issue 5, Pages 514–524 (Mi nano1134)

This article is cited in 2 papers

CHEMISTRY AND MATERIAL SCIENCE

Formation, structure, composition in the dispersed state, and behavior of nanoparticles heated in the Mg(OH)$_2$ – Ni(OH)$_2$ system

Maria E. Kotovaab, Tatiana P. Maslennikovaab, Valery L. Ugolkova, Victor V. Gusarovab

a I. V. Grebenshchikov Institute of Silicate Chemistry of the Russian Academy of Sciences, St. Petersburg, Russia
b V. I. Ulyanov St. Petersburg State Electrotechnical University "LETI", St. Petersburg, Russia

Abstract: The effect of nickel content in Mg$_{1-x}$Ni$_{x}$(OH)$_{2}$ nanoparticles produced by reverse co-precipitation on their structural characteristics, morphology and size parameters of crystallites and particles has been studied. The plate-shaped nanoparticles were shown to be predominantly single crystals. It has been determined that when the nickel content $x$ in the hydroxide solid solution is not less than 0.4, the particle size sharply decreases and the number of stacking faults increases. The dependence of the dehydration temperature of Mg$_{1-x}$Ni$_{x}$(OH)$_{2}$ nanoparticles on the nickel content has been revealed.

Keywords: magnesium hydroxide, nickel hydroxide, layered double hydroxide, nanoparticles.

Received: 18.08.2022
Revised: 06.10.2022
Accepted: 11.10.2022

Language: English

DOI: 10.17586/2220-8054-2022-13-5-514-524



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