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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2023 Volume 14, Issue 1, Pages 120–126 (Mi nano1170)

This article is cited in 4 papers

CHEMISTRY AND MATERIAL SCIENCE

Influence of using different types of microreactors on the formation of nanocrystalline BiFeO$_3$

Olga V. Proskurinaab, Rufat Sh. Abievab, Vladimir N. Nevedomskiya

a Ioffe Institute, St. Petersburg, Russia
b St. Petersburg State Institute of Technology, St. Petersburg, Russia

Abstract: The influence of the coprecipitation of bismuth and iron hydroxides in microreactors of various types on the formation of nanocrystalline bismuth orthoferrite during the heat treatment of the deposit was described. Free impinging-jets microreactor, microreactor with submerged jets, microreactor with intensively swirling flows were used. It was revealed that nanocrystalline bismuth orthoferrite with the smallest weighted average crystallite size of 12 nm is formed when a microreactor with tangentially swirling flows of reagent solutions is used for coprecipitation of hydroxides. The minimum size of BiFeO$_3$ crystallites according to transmission electron microscopy data is determined as 3–4 nm.

Keywords: free impinging-jets microreactor, microreactor with submerged jets, microreactor with intensively swirling flows, nanocrystals, bismuth ferrite.

Received: 27.09.2022
Revised: 10.10.2022
Accepted: 30.10.2022

Language: English

DOI: 10.17586/2220-8054-2023-14-1-120-126



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© Steklov Math. Inst. of RAS, 2024