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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2024 Volume 15, Issue 5, Pages 710–715 (Mi nano1315)

CHEMISTRY AND MATERIAL SCIENCE

Synthesis of CdSTe nanoparticles by laser ablation

Maarif A. Jafarov, Vagif M. Salmanov, Rovshan M. Mamedov, Elshan F. Nasirov, Turana A. Mammadova

Baku State University, AZ1148 Baku, Azerbaijan

Abstract: Synthesis of CdSTe nanoparticles using CdCl$_2$, Na$_2$S$_2$O$_3$ and TeO$_2$ solutions under the action of laser radiation was experimentally studied. The radiation source was a pulsed Nd:YAG laser with built-in generators of the 2nd and 3rd harmonics, designed to generate radiation with a wavelength of 1064, 532, and 335 nm. The laser pulse duration was 10 ns with an energy of 135 mJ per pulse. In a colloidal solution, the formation of nanoparticles with a diameter of 10 to 50 nm was observed. X-ray diffraction analysis established that the crystal structure of the nanoparticles is the same as that of the bulk material (hexagonal). It is shown that the photoluminescence emission of the obtained nanoparticles has a green color ($\sim$560 nm) and is associated with the radiative recombination of free excitons.

Keywords: CdSTe nanoparticles, laser ablation, photoluminescence.

Received: 07.04.2024
Revised: 22.08.2024
Accepted: 26.09.2024

Language: English

DOI: 10.17586/2220-8054-2024-15-5-710-715



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