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JOURNALS // Nanosystems: Physics, Chemistry, Mathematics // Archive

Nanosystems: Physics, Chemistry, Mathematics, 2025 Volume 16, Issue 1, Pages 116–122 (Mi nano1350)

CHEMISTRY AND MATERIAL SCIENCE

Synthesis, structure and noncovalent interactions of mesityl(phenyl)phosphine oxide glycolate based hydrogen-bonded nanosized organic framework

Alexey A. Kagileva, Ilyas F. Sakhapova, Zufar N. Gafurova, Artyom O. Kantyukovab, Ilya K. Mikhailova, Daut R. Islamovc, Alexander V. Gerasimovb, Oleg A. Filippovd, Aidar T. Gubaidullina, Olga S. Sofichevaa, Oleg G. Sinyashina, Dmitry G. Yakhvarovab

a Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russian Federation
b A.M. Butlerov Institute of Chemistry, Kazan Federal University, 420008, Kazan, Russian Federation
c Laboratory for Structural Studies of Biomacromolecules, FRC Kazan Scientific Center, Russian Academy of Sciences
d A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russian Federation

Abstract: The reaction of glyoxylic acid monohydrate with mesityl(phenyl)phosphine in air led to the formation of mesityl(phenyl)phosphine oxide glycolate. The synthesized mesityl(phenyl)phosphine oxide glycolate has been characterized by various analytical methods including X-ray crystal structure analysis. The analysis of intermolecular interactions in the crystal revealed interesting modes of the noncovalent bonding between pairs of molecules. These intermolecular interactions cause the formation of one-dimensional cylindrical channels with diameter of $1$ nm ($10\mathring{\mathrm{A}}$) and provide the crystal with the properties of precise nano-sized crystalline porous material which can be served as the component for precise nanofiltration membranes improving the properties of amorphous polymers which suffer from disordered pore structures and reduced selectivity towards separating molecules.

Keywords: phosphine, phosphine oxide, glycolate, X-ray diffraction, noncovalent bonding.

Received: 20.12.2024
Revised: 11.02.2025
Accepted: 12.02.2025

Language: English

DOI: 10.17586/2220-8054-2025-16-1-116-122



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© Steklov Math. Inst. of RAS, 2025